Materials Sodium hyaluronate (CAS: 9004-61-9), gelatin (CAS: 9000-70-8), sodium alginate (CAS: 9005-38-3), tetraethyl orthosilicate (TEOS, CAS: 78-10-4), copper nitrate trihydrate (Cu(NO 3 ) 2 3H 2 O, CAS: 10031-43-3), zinc nitrate hexahydrate (Zn(NO 3 ) 2 6H 2 O, CAS: 10196-18-6), ammonium fluoride (NH 4 F, CAS: 12125-01-8), cetyltrimethylammonium bromide (CTAB, CAS: 57-09-0), zinc chloride (ZnCl 2 , CAS: 7646-85-7), copper chloride (CuCl 2 , CAS: 10125-13-0), and sodium silicate (Na 2 SiO 3 , CAS: 13517-24-3) were purchased from Sinopharm Chemical Reagent Co., Ltd (Shanghai, China)
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